Tom is correct: doing everything with vectors is the easiest.
without vectors you could do i & ii easily though:
i) By definition of a square prism, ABCD is orthogonal to AA'C'C and therefore BD is perpendicular to A'C. QED.
ii) Consider ABCD: given AD=2, DC=2*(3^0.5) AD perpendicular to DC, therefore by Pythagoras' Theorem AC=4.
AC perpendicular to BD therefore AC * DE = AD * DC
DE = 3^.5
Consider the rectangle AA'C'C, which is orthogonal to both A'BD and BC'D and therefore the angle between both planes is the angle between A'E and EC'
By Pythagoras' Theorem:
A'E = 2, EC' = 2*(3^0.5) and therefore A'EC' is a right angle.
The angle between A'BD and BC'D is 90deg.
iii) we'll have to do this vector-style.
Frame of reference:
i // EC, j // EB, k // AA'
therefore the vectors: AD = (i -3^0.5j 0) and BC' (3i -3^0.5j 3^0.5k)
let the containing angle = a, therefore:
cos a = (AD.BC') / (|AD| * |BC'|)
cos a = 6 / (2 * 15^0.5)
a = arc cos (6 / (2 * 15^0.5))
And at this point I'm just too lazy to run the number through the calculator
Edited to insert i, j, k