turbof1 wrote:
@WilliamsF1: I'm by no means an expert, but I believe the NOx is a byproduct simply by burning diesel, like CO2 is a byproduct when burning gasoline. Lean burn will probably cause more NOx emissions, but note that that same lean burn has a higher efficiency and allows for more horsepower. Having a less le burn will drop both fuel economy and power.
NOX is not a product of ‘lean burn’. In fact the exact opposite - rich burn and lean burn are NOx mitigating strategies. If you are to draw a graph with NOx on Y axis and Equivalence ratio on X axis – you will end up with a bell shaped normal distribution curve – with peak production occurring at Eq. ratio = 1 and NOx drastically falling away on either sides (lean and rich).
The concept of ‘lean burn’ does not hold good for diesel combustion anyway – because what lengthscale will you consider to base this on? If you take the combustion chamber as a whole – its always lean as you are smoke limited in Diesels and the AFRs are high. Its your local Eq ratio in the vicinity of the spray that matters in diesel combustion regimes. And over here the fuel is highly stratified. You do not have one flame front like that of PFI or during the homogenous mode of a GDI – instead multiple local ones hanging around individual droplets, and combustion occurring everywhere you have the atomised fuel.
WilliamsF1 wrote:
NOx is a product of lean burn or is it?
So in all probability the top end would not change.
Unless Nitrogen is present the fuel – such as coal, wood etc which would give rise to additional sources of NOx - almost all of the NOx for automobiles is thermal NOx. The atmosphere contains ~78% nitrogen. So anything that burns in air will produce NOx as long as the adiabatic flame temperature is higher than 1700-1800K range – from a cigarette lighter to jet engines.
The components of Nox are the active NO species and passive NO2. 60-90% of NOx is NO. (depending on speed-load conditions). While temperature is the driving factor for this 'zeldovich mechanism' - NO formation is a 2 way reaction - there is production and decomposition. And this balance between NO production and decomposition is a factor of species concentrations on the flame surface, local pressure, temp, local eq ratio etc. During the expansion stroke - as the piston moves past 50-60 deg CA ATDC - the gasses cool down <1700K and the zeldovich mechanism is kinetically limited - you have what is called as NOx freeze and it just hangs in there until exhaust valve opens. So all the NOx is formed from the point of injection till about 60deg CA.